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RPCS3 is a great emulator! They can be a pain to set up or tweak for performance but that one in particular is a very smooth experience.
Having some trouble getting peace walker going on the emulator. Not a lot of issues to find while searching either. Bazzite on either AMD or Intel with Nvidia GPUs.
So in the meantime, we have dusted off the PS3 to use my mgs4 disc hah!