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Absolutely it could. Vest or no vest, I don’t want to get shot. But “aim for center of mass” is only the rule of thumb when the center of mass is unprotected. Otherwise, it becomes “aim for the material specifically designed to stop bullets” which is not a great rule of thumb.
It also depends on the bullet and rifle, I kinda doubt there are many bullet proof vests that can br qord under clothes that can hold up against a .308.
But im gonna hazard a guess that some 20 year old trying to do an assassination was probably using an AR-15 chambered in 5.56. Which I would coin flip on if the vest could handle it or not.