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They definitely could, but most cybersecurity departments are paid too much to worry about minor items like that. If HR tells us to look into a specific user and gets the proper approvals so that everything is in compliance, we’ll definitely get someone on the team to do it, but otherwise if we happen to see evidence of unapproved usage, we’re mostly going to overlook it unless it could lead to something dangerous to your machine or the company as a whole.
EDRs like Crowdstrike can see very very nearly everything you do though, definitely everything you would care about.