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Trees never evolved for the purposes of mass capturing carbon from the air as efficiently as possible. Yes, they convert CO2 to O2 as part of their life cycle, but algae and other organisms have a much bigger role in capturing CO2 and turning it into O2.
Furthermore, so much of the CO2 that we emit is CO2 that was sequestered in the past over those very same 100s of millions of years. Meaning that going the natural route will take that amount of time.