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The way I understand “Smalltalk” is not whether the subject matter is “serious enough” but rather whether either party actually has any interest in it, or if it is a polite nicety to avoid awkward silence.
Discussing the weather in a car ride with a coworker is smalltalk, contemplating with a friend how one might conquer the world using ant-controlling super powers is not.
This exactly. “Do you think free will exists” could, in fact, be small talk, if neither of you is particularly interested in the topic.