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If you have literally no experience at all, I’d pick and choose some great standalone episodes to get started with.
Some ideas: TOS: Balance of terror/Space seed. TNG: Drumhead/Darmok. DS9: The House of Quark/Trials and tribulations (harder to find good standalone episodes as so many of the best are part of the main plot. VOY: Eye of the Needle/The Void.
The 2 parter DS9 and voyager opening episodes are both also pretty good places to start.
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